副教授 –唐生表
Email : shengbiaotang@cczu.edu.cn
教育经历:
2013/07-2016/06，北京大学-天津大学 联合培养（博士），导师：叶新山教授
2011/09-2013/06，天津大学（硕士），导师：姜申德教授
工作经历：
2018/09-至今，澳洲威尼斯精品区
2016/06-2018/08，中科院上海有机化学研究所，博士后，合作导师：游书力研究员
研究方向:
不对称合成，过渡金属催化
教学科研项目:
(1) 国家自然科学基金委员会, 面上项目, 21971026, 基于金属卡宾的含氮杂环不对称N-烷基化反应研究, 2020-01-01 至 2023-12-31, 65万元, 在研, 参与（排名第二）。
(2) 国家自然科学基金委员会, 青年科学基金项目, 21901022, 二烯化合物的区域及对映选择性胺基化反应研究, 2020-01-01 至 2022-12-31, 25万元, 在研, 主持。
近期发表论文
1) Tang, Shengbiao, * Zhang, Peng, Shao, Ying, Sun, Jiangtao, Enyne Diketones As New Classes Substrate in Asymmetric Nazarov Cyclization for Construction of Chiral Allene Cyclopentenone. Nat. Commun.2022, 13, 3146.Nat. Commun. 2022, 13, 3146.
2) Tang, Shengbiao, * Zhang, Peng, Wang, Changkai, Shao, Ying, Sun, Jiangtao, Iridium-catalyzed regio- and enantioselective allylic esterification of secondary allylic alcohols with carboxylic acids, Chem. Commun., 2021, 57, 11080-11083.
3) Shengbiao Tang,* Jianliang Yu, Ying Shao, Jiangtao Sun.* Scandium-catalyzed highly selective N2-alkylation of benzotriazoles with cyclohexanones，Org. Chem. Front., 2021, 8, 278-282.
4) Shengbiao Tang, Ziyong Li, Ying Shao, Jiangtao Sun.* Ir-Catalyzed Regiocontrolled Allylic Amination of Di-/Trienyl Allylic Alcohols with Secondary Amines, Org. Lett. 2019, 21, 18, 7228-7232.
5) Sheng-Biao Tang, Hang-Fei Tu, Xiao Zhang, and Shu-Li You.* Rhodium-Catalyzed Asymmetric Allylic Dearomatization of β-Naphthols: Enantioselective Control of Prochiral Nucleophiles. Org. Lett. 2019, 21, 6130−6134.
6) Sheng-Biao Tang, Xiao Zhang, Hang-Fei Tu, and Shu-Li You.* Regio- and Enantioselective Rhodium-Catalyzed Allylic Alkylation of Racemic Allylic Alcohols with 1,3-Diketones. J. Am. Chem. Soc. 2018, 140, 1137-1142.
7) Shengbiao Tang, Qiannan Zheng, De-Cai Xiong, Shende Jiang, Qin Li, and Xin-Shan Ye*. Stereocontrolled Synthesis of 2-Deoxy-C-glycopyranosyl Arenes Using Glycals and Aromatic Amines. Org. Lett. 2018, 20, 3079-3082.
8) Shengbiao Tang, De-Cai Xiong, Shende Jiang, and Xin-Shan Ye*. Nitro-polyols via Pyridine Promoted C=C Cleavage of 2-Nitroglycals. Application to the Synthesis of (-)-Hyacinthacine A1. Org. Lett. 2016, 18, 568–571.
9) Guangyang Xu, Ping Chen, Pei Liu, Shengbiao Tang, Xinhao, Zhang, Jiangtao Sun,* Access to N-Substituted 2-Pyridones by Catalytic Intermolecular Dearomatization and 1,4-Acyl Transfer. Angew. Chem. Int. Ed. 2019, 58, 1980-1984.
10) Kai Wang, Jianliang Yu, Ying Shao, Shengbiao Tang, Jiangtao Sun,* Forming All-Carbon Quaternary Stereocenters by Organocatalytic Aminomethylation: Concise Access to beta(2,2)-Amino Acids. Angew. Chem. Int. Ed. 2020, 59, 23516-23520.
11) Chemo- and Enantioselective Insertion of Furyl Carbene into the N-H Bond of 2-Pyridones. Wang K.; Liu, Z.; Xu, G.; Shao, Y.; Tang, S.; Chen, P.; Zhang, X.;* Sun, J.*. Angew. Chem. Int. Ed. 2021, 60, 16942-16946.
12) Construction of C-C Axial Chirality via Asymmetric Carbene Insertion into Arene C-H Bonds. Li, Z.; Chen, Y. Wang, C.; Xu, G.; Shao, Y.; Zhang, X.;* Tang, S.; Sun, J.* Angew. Chem. Int. Ed. 2021, 60, 25714-25718.
授权专利：
(1) 唐生表; 苏家慧; 孙江涛 ; 一种苯并三氮唑及其衍生物高选择性N2烷基化方法, 中国, CN202010541148.1
(2) 唐生表; 张鹏; 孙江涛 ; 合成环外联烯醇化合物的方法, 中国, ZL202110305142.9
